Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

An experimental approach for determination of the Weibull homogeneity index of rock or rock-like materials     

Pan  Xiaohua  Guo  Wei  Wu  Shifan  Chu  Jian 《Acta Geotechnica》2020,15(2):375-391

Acta Geotechnica - The spatial variation of the physical–mechanical properties of rock or rock-like materials is an intrinsic characteristic of the materials induced by multiscale material...  相似文献   

木本植被覆盖岸坡上波浪爬升过程的数值模拟研究   总被引：1，自引：1，他引：0  

徐海珏  胡萍  白玉川  杨波 《海洋学报》2020,42(3):10-24

近岸木本植物构成的生态缓冲带作为新型的海岸软防护结构，兼具功能性和生态友好性，在沿海工程建设中愈发受到关注，如何深入开展其防护效果的机理研究是目前亟待解决的问题。本文采用数值模拟方法，在N-S方程中分别考虑树枝和树干的拖曳力影响，提出了木本植被作用下波浪沿斜坡爬升的表面波衰减的连续介质等效模型，并采用MAC法来跟踪自由曲面上的水颗粒轨迹。本文以波浪沿1/30的斜坡爬升为算例，对比讨论了有无植被作用下波浪的传播过程，并将算例结果与以往试验结果规律进行对照，验证了数值模型的有效性。最后，分别讨论了植物枝干的高度、密度、树枝倾斜角度等植被特性和波浪因素对植被消浪效果的影响，得到植被消浪的基本规律。文中的计算结果也可为实际的护岸工程和生态景观设计提供参考。  相似文献   

长江口咸潮入侵变化特征及成因分析     

李文善  王慧  左常圣  董军兴  徐浩  潘嵩  金波文  高通 《海洋学报》2020,42(7):32-40

本文基于海洋站潮位观测数据、海平面变化影响调查信息以及长江口水文站径流量数据等，重点分析了2009?2018年长江口咸潮入侵的变化特征及其影响因素，分析结果表明:(1)长江口咸潮入侵季节变化特征明显。咸潮一般从每年的9?10月开始入侵，翌年4?5月结束。3月咸潮入侵次数最多，达12次。2009?2018年，长江口咸潮入侵次数和咸潮持续时间均呈下降趋势，2009年长江口咸潮入侵次数最多，达13次，时间均发生在10月至翌年的4月；咸潮持续时间年际变化较大，2011年咸潮入侵持续时间最长，累计为55 d。2015?2018年，咸潮入侵次数和入侵持续时间均明显减少，2018年没有监测到咸潮入侵过程。(2) 1?4月，长江口处于季节性低海平面期，且同期径流量少，但是受东亚季风影响，持续的增水过程使得增减水?径流量综合影响指数明显偏高，其中1月、2月、3月的影响指数分别为1.5、1.9和1.6，该时段长江口的咸潮入侵过程主要受增减水的影响。5?7月，长江口径流量明显增加，海平面?径流量综合影响指数均小于0，径流的作用强于海水上溯。8月，长江口径流量开始下降，虽然季节海平面较高，但是长江口呈现明显的减水过程，海平面?径流量和增减水?径流量的综合影响指数分别为0.1和?1.6，基本不会发生咸潮入侵。9月，长江口处于季节高海平面期，并且以增水为主，海平面?径流量和增减水?径流量的综合影响指数较大，分别为1.2和1.0，易发生咸潮入侵。10月、11月长江口海平面?径流量的综合影响指数分别为1.5和0.8，径流影响弱于海水上溯，易发生咸潮入侵。(3) 2009?2018年发生的48次咸潮入侵过程有2/3恰逢天文大潮。在某些年份长江口沿海基础海平面偏高，若持续增水恰逢天文大潮，则加剧咸潮入侵的影响程度。  相似文献   

中尺度暖涡对热带气旋强度变化的影响及作用机制   总被引：1，自引：0，他引：1  

孙佳  王桂华  熊学军  回贞立  胡筱敏  凌征  于龙  杨光兵  郭延良  鞠霞  陈亮 《海洋学报(英文版)》2020,39(8):1-2

基于两组理想化数值试验，对比研究了分布于热带气旋不同位置处的海洋中尺度暖涡所引发的热带气旋强度变化的时空特征。研究发现，热带气旋中心附近的暖涡对热带气旋强度有增强作用，而位于热带气旋外围的暖涡则会抑制热带气旋的发展。本研究将暖涡增强（减弱）热带气旋强度的区域称为内（外）区。随着时间的推移，内（外）区暖涡对热带气旋强度的增强（减弱）幅度逐渐减小（增大），区域范围同步减小（增大）。内区暖涡增强了热带气旋的次级环流和结构对称性、增加了海气界面热通量，同时减弱了外围螺旋雨带，进而导致热带气旋强度增强；若暖涡在外区，其对热带气旋的作用相反，导致热带气旋强度减弱。由于理想化试验中热带气旋静止不动，因此研究结果可能只适用于传播速度较慢的热带气旋。本研究结果有助于更好地理解热带气旋和海洋中尺度暖涡之间的相互作用，并通过引入热带气旋外区暖涡的影响助力提高热带气旋强度预报工作。  相似文献   

渤海海域浮游病毒和浮游细菌的丰度变化与环境因子之间的耦联关系     

王彩霞  吴霖  王毅波  Paterson James S.  Mitchell James G.  胡晓珂 《海洋学报(英文版)》2020,39(6):72-83

Uncovering the role of environmental factors and finding critical factors which harbor significant fractions in governing microbial communities remain key questions in coastal marine systems. To detect the interactions between environmental factors and distributions of virio-and bacterioplankton in trophic coastal areas, we used flow cytometry to investigate the abundance of virio-and bacterioplankton covering 31 stations in the Bohai Sea of China. Our results suggested that the average abundance of total virus(TV) in winter(～2.29×10~8 particles/mL)was slightly lower than in summer(～3.83×10~8 particles/mL). The mean total bacterial abundance(TB) was much lower in winter(～2.54×107 particles/mL) than in summer(～5.43×10~7 particles/mL). Correlation analysis via redundancy analysis(RDA) and network analysis among virioplankton, bacterioplankton and environmental factors revealed that the abundances of viral and bacterial subpopulations depend on environmental factors. In winter, only temperature significantly influenced the abundances of virio-and bacterioplankton. In summer, in addition to temperature, both salinity and nutrient(SiO_2) had a remarkable impact on the distribution of virioand bacterioplankton. Our results showed a clear seasonal and trophic pattern throughout the whole water system, which revealed that temperature and eutrophication may play crucial roles in microbial distribution pattern.  相似文献   

基于拉格朗日拟序结构的吕宋海峡表层水交换研究     

郑哲昊  庄伟  胡建宇  吴泽轮  刘长建 《海洋学报(英文版)》2020,39(11):21-32

黑潮通过吕宋海峡入侵南海呈现明显的瞬态特征。以往的研究通常将黑潮在吕宋海峡附近的流态分为几种不同类型。本文基于表层地转流计算得到的有限时间李雅普诺夫指数场（FTLE），展示了拉格朗日视角下的吕宋海峡上层水交换特征。从FTLE场提取的拉格朗日拟序结构（LCSs）很好地识别了吕宋海峡附近的典型流态和旋涡活动。此外，这些LCSs还揭示了吕宋海峡周围复杂的输运路径和流体域，这些特征得到了卫星跟踪浮标轨迹的验证，且从流速场中是无法直接识别的。FTLE场显示，吕宋海峡附近表层水体的输运形态主要可分为四类。其中，黑潮直接向北流动的“跨越”形态和顺时针旋转的“流套”形态的发生频次明显高于直接进入南海的黑潮分支“渗入”形态和南海水流出至太平洋的“外流”形态。本文还进一步分析了黑潮在吕宋海峡处的涡旋脱落事件，突出强调了LCSs在评估涡旋输运方面的重要性。反气旋涡旋的脱落个例表明，这些涡旋主要源自黑潮“流套”，涡旋脱落之前可有效地俘获黑潮水。LCS所指示的输运通道信息有助于预测最终被反气旋涡所挟卷水体在上游的位置。而在气旋涡的形成过程中，LCS的分布特征表明，大部分气旋涡并未与黑潮水的输运路径相连通。因此，气旋涡对从太平洋到南海的上层水交换的贡献较小。  相似文献   

A new evil waveforms evaluating method for new BDS navigation signals     

Chengyan He  Ji Guo  Xiaochun Lu  Xue Wang  Yongnan Rao  Li Kang  Zhigang Hu 《GPS Solutions》2018,22(2):37

With the advent of new global navigation satellite systems (GNSSs) and new signals, GNSS users will rely more on them to obtain higher-accuracy positioning. Evil waveform monitoring and assessment are of great importance for GNSS to achieve its positioning, velocity, and timing service with high accuracy. However, the advent of new navigation signals introduces the necessity to extend the traditional analyzing techniques already accepted for binary phase-shift keying modulation to new techniques. First, the well-known second-order step thread model adopted by the International Civil Aviation Organization is introduced. Then the extended new general thread models are developed for the new binary offset carrier modulated signals. However, no research has been done on navigation signal waveform symmetry yet. Simulation results showed that, waveform asymmetry may also cause tracking errors, range biases, and position errors in GNSS receivers. It is thus imperative that the asymmetry be quantified to enable the design of appropriate error budgets and mitigation strategies for various application fields. A novel evil waveform analysis method, called waveform rising and falling edge symmetry (WRaFES) method, is proposed. Based on this WRaFES method, the correlation metrics are provided to detect asymmetric correlation peaks distorted by received signal asymmetry. Then the statistical properties of the proposed methods are analyzed, and a proper deformation detection threshold is calculated. Finally, both simulation results and experimentally measured results of Beidou navigation satellite system (BDS) M1-S B1Cd signal are given, which show the effectiveness and robustness of the proposed thread models.  相似文献   

Initial results of centralized autonomous orbit determination of the new-generation BDS satellites with inter-satellite link measurements   总被引：3，自引：0，他引：3  

Chengpan Tang  Xiaogong Hu  Shanshi Zhou  Li Liu  Junyang Pan  Liucheng Chen  Rui Guo  Lingfeng Zhu  Guangming Hu  Xiaojie Li  Feng He  Zhiqiao Chang 《Journal of Geodesy》2018,92(10):1155-1169

Autonomous orbit determination is the ability of navigation satellites to estimate the orbit parameters on-board using inter-satellite link (ISL) measurements. This study mainly focuses on data processing of the ISL measurements as a new measurement type and its application on the centralized autonomous orbit determination of the new-generation Beidou navigation satellite system satellites for the first time. The ISL measurements are dual one-way measurements that follow a time division multiple access (TDMA) structure. The ranging error of the ISL measurements is less than 0.25 ns. This paper proposes a derivation approach to the satellite clock offsets and the geometric distances from TDMA dual one-way measurements without a loss of accuracy. The derived clock offsets are used for time synchronization, and the derived geometry distances are used for autonomous orbit determination. The clock offsets from the ISL measurements are consistent with the L-band two-way satellite, and time–frequency transfer clock measurements and the detrended residuals vary within 0.5 ns. The centralized autonomous orbit determination is conducted in a batch mode on a ground-capable server for the feasibility study. Constant hardware delays are present in the geometric distances and become the largest source of error in the autonomous orbit determination. Therefore, the hardware delays are estimated simultaneously with the satellite orbits. To avoid uncertainties in the constellation orientation, a ground anchor station that “observes” the satellites with on-board ISL payloads is introduced into the orbit determination. The root-mean-square values of orbit determination residuals are within 10.0 cm, and the standard deviation of the estimated ISL hardware delays is within 0.2 ns. The accuracy of the autonomous orbits is evaluated by analysis of overlap comparison and the satellite laser ranging (SLR) residuals and is compared with the accuracy of the L-band orbits. The results indicate that the radial overlap differences between the autonomous orbits are less than 15.0 cm for the inclined geosynchronous orbit (IGSO) satellites and less than 10.0 cm for the MEO satellites. The SLR residuals are approximately 15.0 cm for the IGSO satellites and approximately 10.0 cm for the MEO satellites, representing an improvement over the L-band orbits.  相似文献   

Three-frequency BDS precise point positioning ambiguity resolution based on raw observables   总被引：1，自引：0，他引：1  

Pan Li  Xiaohong Zhang  Maorong Ge  Harald Schuh 《Journal of Geodesy》2018,92(12):1357-1369

All BeiDou navigation satellite system (BDS) satellites are transmitting signals on three frequencies, which brings new opportunity and challenges for high-accuracy precise point positioning (PPP) with ambiguity resolution (AR). This paper proposes an effective uncalibrated phase delay (UPD) estimation and AR strategy which is based on a raw PPP model. First, triple-frequency raw PPP models are developed. The observation model and stochastic model are designed and extended to accommodate the third frequency. Then, the UPD is parameterized in raw frequency form while estimating with the high-precision and low-noise integer linear combination of float ambiguity which are derived by ambiguity decorrelation. Third, with UPD corrected, the LAMBDA method is used for resolving full or partial ambiguities which can be fixed. This method can be easily and flexibly extended for dual-, triple- or even more frequency. To verify the effectiveness and performance of triple-frequency PPP AR, tests with real BDS data from 90 stations lasting for 21 days were performed in static mode. Data were processed with three strategies: BDS triple-frequency ambiguity-float PPP, BDS triple-frequency PPP with dual-frequency (B1/B2) and three-frequency AR, respectively. Numerous experiment results showed that compared with the ambiguity-float solution, the performance in terms of convergence time and positioning biases can be significantly improved by AR. Among three groups of solutions, the triple-frequency PPP AR achieved the best performance. Compared with dual-frequency AR, additional the third frequency could apparently improve the position estimations during the initialization phase and under constraint environments when the dual-frequency PPP AR is limited by few satellite numbers.  相似文献